Revealing the peculiar local behavior of manganese and cobalt in diffusion-doped calcium orthovanadate Ca3(VO4)2-Reference-Cited by-同舟云学术

Revealing the peculiar local behavior of manganese and cobalt in diffusion-doped calcium orthovanadate Ca₃(VO₄)₂

Published:2022 Issue:14 Volume:51 Page:5673-5686
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kuz'micheva Galina M.¹,Ivleva Liudmila I.²^ORCID,Kaurova Irina A.¹^ORCID,Khramov Evgeny V.³^ORCID,Lazarenko Vladimir A.³^ORCID,Rybakov Victor B.⁴^ORCID,Svetogorov Roman D.³,Doroshenko Maxim E.²

Affiliation:

1. MIREA – Russian Technological University, 78 Vernadsky ave., Moscow 119454, Russia

2. Prokhorov General Physics Institute, Russian Academy of Sciences, 38 Vavilova str., Moscow 119991, Russia

3. National Research Center “Kurchatov Institute”, 1 Akademika Kurchatova pl., Moscow 123182, Russia

4. Lomonosov State University, 1-3 Vorobyovy Gory, Moscow 119992, Russia

Abstract

The local environment of manganese and cobalt in diffusion doped Ca3(VO4)2 crystals was experimentally evidenced: tetrahedral coordination and the coordination intermediate between tetrahedral and octahedral was revealed for Mn(2+δ)+ and Co2+ ions.

Funder

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT03799D

Reference51 articles.

1. Calcium orthovanadate, Ca3(VO4)2-a new high-temperature ferroelectric

2. Elastic, thermoelastic, piezoelectric, linear electrooptic, dielectric, and pyroelectric properties of trigonal Ca3(VO4)2single crystals

3. Spectroscopic and laser properties of Tm3+ ions in Ca3(VO4)2 crystal