Iridium-catalyzed selective arylation of B(6)–H of 3-aryl-<i>o</i>-carboranes with arylboronic acid <i>via</i> direct B

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Iridium-catalyzed selective arylation of B(6)–H of 3-aryl-o-carboranes with arylboronic acid via direct B–H activation

Published:2024 Issue:9 Volume:60 Page:1124-1127
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Yang Han-Bo¹,Guo Yan²,Cao Ke¹^ORCID,Jiang Qi-Jia¹,Teng Chao-Chao¹,Zhu Dao-Yong³^ORCID,Wang Shao-Hua³^ORCID

Affiliation:

1. State Key Laboratory of Environment-friendly Energy Materials & School of Materials and Chemistry, Southwest University of Science and Technology, 59 Qinglong Road, Mianyang, Sichuan, P. R. China

2. Department of Oncology, Sichuan Science City Hospital, Mianyang, Sichuan, 621000, P. R. China

3. School of Pharmacy & State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China

Abstract

This work discloses an iridium-catalyzed selective arylation of B(6)–H of 3-Ar-o-carboranes with arylboronic acid via direct B–H activation for the first time.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Sichuan Province

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D3CC05630A

Reference58 articles.

1. Electrochemistry and Photoluminescence of Icosahedral Carboranes, Boranes, Metallacarboranes, and Their Derivatives

2. Nonclassical Applications of closo-Carborane Anions: From Main Group Chemistry and Catalysis to Energy Storage

3. Icosahedral boron clusters: a perfect tool for the enhancement of polymer features

4. Carboranes as a Tool to Tune Phosphorescence

5. Boron clusters in luminescent materials

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