The chelate-to-bridging shift of phosphane dipalladacycles: convenient synthesis of double A-frame tetranuclear complexes

Author:

Frieiro-Gomis Pablo1234,Lucio-Martínez Fátima1234ORCID,Munín-Cruz Paula1234,Ortigueira Juan M.1234ORCID,Pereira M. Teresa1234ORCID,Polo-Ces Paula1234,Vázquez-García Digna56784ORCID,Vila José M.1234ORCID

Affiliation:

1. Departamento de Química Inorgánica

2. Universidade de Santiago de Compostela

3. 15782 Santiago de Compostela

4. Spain

5. Departamento de Química Fundamental and Centro de Investigacións Científicas Avanzadas (CICA)

6. Facultade de Ciencias

7. Universidade da Coruña

8. E-15071 A Coruña

Abstract

A tailor-made synthetic procedure was devised to produce a four-palladium supramolecular architecture capable of hosting two A-frame moieties.

Funder

Ministerio de Educación, Cultura y Deporte

Consellería de Cultura, Educación e Ordenación Universitaria, Xunta de Galicia

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference39 articles.

1. Cyclometalation Using d-Block Transition Metals: Fundamental Aspects and Recent Trends

2. I. Omae , Cyclometalation Reactions. Five-Membered Ring Products as Universal Reagents , Springer , Japan , 2014

3. J. Tsuji , Palladium Reagents and Catalysts , Wiley , Chichester , 1995

4. I. Omae , Applications of Organometallic Compounds , Wiley , Chichester , 1998

5. Light-emitting devices based on organometallic platinum complexes as emitters

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