Basically, nucleophilicity matters little: towards unravelling the supramolecular driving forces in enzyme-like CO<sub>2</sub> conversion-Reference-Cited by-同舟云学术

Basically, nucleophilicity matters little: towards unravelling the supramolecular driving forces in enzyme-like CO₂ conversion

Published:2022 Issue:33 Volume:20 Page:6637-6645
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Esteve Ferran¹^ORCID,Altava Belén¹^ORCID,Luis Santiago V.¹^ORCID,García-Verdugo Eduardo¹^ORCID

Affiliation:

1. Departamento de Química Inorgánica y Orgánica, Universitat Jaume I, Av. Sos Baynat s/n, Castellón, 12071, Spain

Abstract

The mechanism for the cycloaddition of CO2 to styrene oxide in the presence of an enzyme-like catalytic system has been elucidated, stressing the crucial role of cooperative supramolecular interactions between the whole catalytic pool.

Funder

Ministerio de Educación, Cultura y Deporte

Universitat Jaume I

Ministerio de Ciencia e Innovación

Generalitat Valenciana

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D2OB00948J

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