Te–Te and Te–C bond cleavage reactions using a monovalent gallanediyl-Reference-Cited by-同舟云学术

Te–Te and Te–C bond cleavage reactions using a monovalent gallanediyl

Published:2015 Issue:11 Volume:44 Page:5153-5159
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ganesamoorthy Chelladurai¹²³⁴,Bendt Georg¹²³⁴,Bläser Dieter¹²³⁴,Wölper Christoph¹²³⁴,Schulz Stephan¹²³⁴

Affiliation:

1. Institute of Inorganic Chemistry

2. University of Duisburg-Essen

3. 45117 Essen

4. Germany

Abstract

Te–Te and Te–C bond cleavage occurs in reactions of monovalent LGa (L = [(2,6-i-Pr₂-C₆H₃)NC(Me)]₂CH) with Te, Ph₂Te₂ and i-Pr₂Te. (LGa-μ-Te)₂1, LGa(TePh)₂2 and LGa(i-Pr)Tei-Pr 3 were characterized by heteronuclear NMR (¹H, ¹³C, ¹²⁵Te) and IR spectroscopy and by single crystal X-ray analyses.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00172B

Reference56 articles.

1. Synthesis and characterization of the monomer Ga{(NDippCMe)2CH} (Dipp = C6H3Pri2-2,6): a low valent gallium(i) carbene analogue

2. Bonding and Reactivity of a β-Diketiminate, Gallium(I), Carbene Analogue

3. Theoretical Study of the Reactivities of Neutral Six-Membered Carbene Analogues of the Group 13 Elements

4. Neutral carbene analogues of the heaviest Group 13 elements: Consideration of electronic and steric effects on structure and stability

5. Gallium–boron donor–acceptor bonds

Cited by 15 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Gallium, Indium, and Thallium;Comprehensive Organometallic Chemistry IV;2022

2. The synthesis of cyclometalated platinum(ii) complexes with benzoaryl-pyridines as C^N ligands for investigating their photophysical, electrochemical and electroluminescent properties;Dalton Transactions;2020

3. The unique β-diketiminate ligand in aluminum(i) and gallium(i) chemistry;Dalton Transactions;2020

4. Interaction of Multiple Bonds with NacNacGa: Oxidative Cleavage vs Coupling and Cyclization;Inorganic Chemistry;2019-06-13

5. Facile oxidative addition of O2 and S8 by an indium bis(carbene) analogue;Dalton Transactions;2019