Copper-catalyzed tandem phosphorylative allenylation/cyclization of 1-(o-aminophenyl)prop-2-ynols with the P(O)–H species: access to C2-phosphorylmethylindoles-Reference-Cited by-同舟云学术

Copper-catalyzed tandem phosphorylative allenylation/cyclization of 1-(o-aminophenyl)prop-2-ynols with the P(O)–H species: access to C2-phosphorylmethylindoles

Published:2020 Issue:8 Volume:7 Page:980-986
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Liu Xiao-Yan¹²³⁴⁵,Zou Yun-Xiang¹²³⁴⁵,Ni Hai-Liang⁶⁷⁸⁵,Zhang Jing¹²³⁴⁵,Dong Hong-Bo¹²³⁴⁵,Chen Long¹²³⁴⁵^ORCID

Affiliation:

1. Antibiotics Research and Re-evaluation Key Laboratory of Sichuan Province

2. Sichuan Industrial Institute of Antibiotics

3. Chengdu University

4. Chengdu 610052

5. P. R. China

6. College of Chemistry and Materials Science

7. Sichuan Normal University

8. Chengdu 610066

Abstract

A novel method to synthesize C2-phosphorylmethylindoles via the carbocation formation initiated tandem phosphorylative allenylation/cyclization of 1-(o-aminophenyl)prop-2-ynols with the P(O)–H species has been developed.

Funder

National Natural Science Foundation of China

Sichuan Province Science and Technology Support Program

Chengdu University

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/QO/D0QO00159G

Reference64 articles.

1. Gold-Catalyzed Cycloisomerization Reactions of 2-Tosylaminophenylprop-1-yn-3-ols as a Versatile Approach for Indole Synthesis