Dehydropolymerisation of methylamine borane using highly active rhodium(iii) bis(thiophosphinite) pincer complexes: catalytic and mechanistic insights
Author:
Affiliation:
1. Leibniz-Institut für Katalyse e.V. (LIKAT)
2. 18059 Rostock
3. Germany
Abstract
The bis(thiophosphinite) pincer complexes [(RPSCSPR)Rh(py)(H)(Cl)] (RPSCSPR = C6H4–2,6-(SPR2)2 with R = iPr, 2a and R = Ph, 2b) are highly active precatalysts for the dehydropolymerisation of methylamine borane.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2021/CY/D1CY00124H
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