Alkenes as hydrogen trappers to control the regio-selective ruthenium(ii) catalyzed ortho C–H silylation of amides and anilides-Reference-Cited by-同舟云学术

Alkenes as hydrogen trappers to control the regio-selective ruthenium(ii) catalyzed ortho C–H silylation of amides and anilides

Published:2021 Issue:3 Volume:8 Page:514-521
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Lin Qiao¹²³⁴,Lin Zirui¹²³⁴,Pan Mingxing¹²³⁴,Zheng Qiaojin¹²³⁴,Li Hui¹²³⁴,Chen Xiuwen¹²³⁴,Darcel Christophe⁵⁶⁷⁸⁹^ORCID,Dixneuf Pierre H.⁵⁶⁷⁸⁹^ORCID,Li Bin¹²³⁴⁵^ORCID

Affiliation:

1. School of Biotechnology and Health Sciences

2. Wuyi University

3. Jiangmen 529020

4. P.R. China

5. Univ. Rennes

6. CNRS

7. ISCR (Institut des Sciences Chimiques de Rennes)

8. F-35000 Rennes

9. France

Abstract

A convenient and practical pathway to versatile silylated amides and anilides is described via efficient and selective ruthenium(ii) catalyzed ortho C–H silylation with different alkenes as the hydrogen acceptors.

Funder

National Natural Science Foundation of China

Department of Education of Guangdong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D0QO01031F

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