Solvent dielectric delimited nitro–nitrito photorearrangement in a perylenediimide derivative-Reference-Cited by-同舟云学术

Solvent dielectric delimited nitro–nitrito photorearrangement in a perylenediimide derivative

Published:2022 Issue:30 Volume:13 Page:8860-8870
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Mazumder Aniruddha¹^ORCID,Sebastian Ebin¹^ORCID,Hariharan Mahesh¹^ORCID

Affiliation:

1. School of Chemistry, Indian Institute of Science Education and Research Thiruvananthapuram, Maruthamala P.O., Vithura, Thiruvananthapuram, Kerala, India 695551

Abstract

The unprecedented photorearrangement of nitro-perylenediimide (NO2-PDI) to nitrito-perylenediimide (ONO-PDI) is shown to occur through a cyclic six-membered transition state triggered by visible-light excitation.

Funder

Department of Science and Technology, Ministry of Science and Technology, India

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC02979K

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