Unexpected formation of poly-functionalized fulvenes by the reaction of a tetraaryl[5]cumulene with iodine-Reference-Cited by-同舟云学术

Unexpected formation of poly-functionalized fulvenes by the reaction of a tetraaryl[5]cumulene with iodine

Published:2021 Issue:35 Volume:19 Page:7594-7597
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Hoshi Keita¹,Yasuda Masashi¹,Nakamura Takumi²,Yoshida Yasushi²^ORCID,Ueta Shoko¹,Minagawa Keiji¹,Kawamura Yasuhiko¹,Imada Yasushi¹^ORCID,Yagishita Fumitoshi¹³^ORCID

Affiliation:

1. Department of Applied Chemistry, Tokushima University, 2-1 Minamijosanjima, Tokushima 770-8506, Japan

2. Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan

3. Department of Post-LED Photonics Research, Institute of Post-LED Photonics, 2-1 Minamijosanjima, Tokushima 770-8506, Japan

Abstract

The reaction of tetrakis(p-methoxyphenyl)[5]cumulene with iodine afforded the iodinated fulvene scaffold via iodocyclization followed by unexpected migration of a terminal aryl ring under ambient condition.

Funder

University of Tokushima

Japan Society for the Promotion of Science

Cabinet Office, Government of Japan

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB01270C

Reference30 articles.

1. Bioorganometallic fulvene-derived titanocene anti-cancer drugs

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3. First preparation of low band gap fulvene-modified polynorbornene via ring-opening metathesis polymerization

4. Symmetrical bis(fulvene) chromophores: model compounds for acceptor–donor–acceptor dye architectures

5. Novel D-π-A Chromophores Based on the Fulvene Accepting Moiety

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