One-pot heteroannulation toward phosphaperylene diimides with high luminescence and out-of-plane anisotropy

Author:

Ma Zetong12,Liu Yujian1,Wang Zhaohui1,Jiang Wei1ORCID

Affiliation:

1. Key Laboratory of Organic Optoelectronics and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing, 100084, P. R. China

2. Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou, 510640, P. R. China

Abstract

This work presents a P-heteroannulation strategy on perylene diimides in one pot. The resulting phosphaperylene diimides demonstrate an out-of-plane dipole moment of 8.10 D and high fluorescence quantum yields of up to 94%.

Funder

China Postdoctoral Science Foundation

National Natural Science Foundation of China

Natural Science Foundation of Shandong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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