Formation and reactivity of a unique M⋯C–H interaction stabilized by carborane cages-Reference-Cited by-同舟云学术

Formation and reactivity of a unique M⋯C–H interaction stabilized by carborane cages

Published:2024 Issue:24 Volume:15 Page:9274-9280
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Liu Xin-Ran¹,Cui Peng-Fei¹,García-Rodeja Yago²,Solà Miquel²^ORCID,Jin Guo-Xin¹^ORCID

Affiliation:

1. State Key Laboratory of Molecular Engineering of Polymers, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai, 200433, P. R. China

2. Institut de Química Computacional i Catàlisi, Departament de Química, Universitat de Girona, C/Maria Aurèlia Capmany, 69, 17003 Girona, Spain

Abstract

Broadening carborane applications has consistently been the goal of chemists in this field. Herein, compared to alkyl or aryl groups, a carborane cage demonstrates an advantage in stabilizing a unique bonding interaction: M⋯C–H interaction.

Funder

National Natural Science Foundation of China

Science and Technology Commission of Shanghai Municipality

China Postdoctoral Science Foundation

Generalitat de Catalunya

Ministerio de Ciencia, Innovación y Universidades

Agencia Estatal de Investigación

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC01158A

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