Mono- and bimetallic amidinate samarium complexes – synthesis, structure, and hydroamination catalysis

Author:

Kazeminejad Neda1234,Münzfeld Luca1234,Gamer Michael T.1234,Roesky Peter W.1234ORCID

Affiliation:

1. Institut für Anorganische Chemie

2. Karlsruher Institut für Technologie (KIT)

3. 76131 Karlsruhe

4. Germany

Abstract

Two similar amidinate samarium catalysts were synthesized in order to investigate the difference between a monometallic and a bimetallic system in the catalytic hydroamination cyclization reaction.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference104 articles.

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3. Guanidinate and amidopyridinate rare-earth complexes: Towards highly reactive alkyl and hydrido species

4. F. T. Edelmann , in Adv. Organomet. Chem , ed. F. H. Anthony and J. F. Mark , Academic Press , 2013 , vol. 61 , pp. 55 – 374

5. F. T. Edelmann , in Adv. Organomet. Chem , ed. F. H. Anthony and J. F. Mark , Academic Press , 2008 , vol. 57 , pp. 183–352

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