A green and facile photochemical thiolate-catalyzed strategy for borylation of aryl fluorides with NHC

A green and facile photochemical thiolate-catalyzed strategy for borylation of aryl fluorides with NHC–borane

Published:2024 Issue:5 Volume:11 Page:1462-1468
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Miao Yu-Qi¹²,Pan Qiao-Jing²,Kang Jia-Xin²^ORCID,Dai Xusheng²,Liu Zhenxing³^ORCID,Chen Xuenian²³^ORCID

Affiliation:

1. School of Pharmacy, Xinxiang University, Xinxiang, Henan, 453003, China

2. Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan, China

3. College of Chemistry, Zhengzhou University, Zhengzhou, Henan, China

Abstract

Mild conditions, no photocatalyst, broad substrate scope.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D4QO00058G

Reference64 articles.

1. Complexes of Borane and N-Heterocyclic Carbenes: A New Class of Radical Hydrogen Atom Donor

2. Advances in chemistry of N-heterocyclic carbene boryl radicals

3. Lewis Base–Boryl Radicals Enabled Borylation Reactions and Selective Activation of Carbon–Heteroatom Bonds

4. Synthesis and Reactions of N-Heterocyclic Carbene Boranes

5. Boryl Radical Addition to Multiple Bonds in Organic Synthesis

Cited by 3 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Enhanced Efficiency of Amide‐Substituted Quinuclidine‐Boranes as Hydridic Hydrogen Atom Transfer Catalysts for Photoinduced Hydroalkylation of Unactivated Olefins^†;Chinese Journal of Chemistry;2024-09-10

2. Halogen Atom Transfer-Induced Homolysis of C–F Bonds by the Excited-State Boryl Radical;Journal of the American Chemical Society;2024-08-02

3. Visible Light-Induced 1,2-Diphenyldisulfane-Mediated Defluoroborylation of Polyfluoroarenes;The Journal of Organic Chemistry;2024-03-16