Synthesis and structure of rhodium(i) silyl carbonyl complexes: photochemical C–F and C–H bond activation of fluorinated aromatic compounds-Reference-Cited by-同舟云学术

Synthesis and structure of rhodium(i) silyl carbonyl complexes: photochemical C–F and C–H bond activation of fluorinated aromatic compounds

Published:2015 Issue:20 Volume:44 Page:9450-9469
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zámostná Lada¹²³⁴,Sander Stefan¹²³⁴,Braun Thomas¹²³⁴,Laubenstein Reik¹²³⁴,Braun Beatrice¹²³⁴,Herrmann Roy¹²³⁴,Kläring Paul¹²³⁴

Affiliation:

1. Humboldt-Universität zu Berlin

2. Department of Chemistry

3. D-12489 Berlin

4. Germany

Abstract

Rhodium(i) silyl carbonyl complexes such as [Rh{Si(OEt)₃}(CO)(dippe)] turned out to be a suitable precursor for the photochemical C–F and C–H bond activation of fluorinated aromatic compounds.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00819K

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4. Activation of the Si-Si Bond by Transition Metal Complexes

5. POP-Pincer Silyl Complexes of Group 9: Rhodium versus Iridium

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