In situ control of photochromic behavior through dual photo-isomerization using cobaloxime complexes with a spiropyran derivative and 2-cyanoethyl ligands

Author:

Sekine Akiko12345ORCID,Tanaka Masato12345,Uekusa Hidehiro12345,Yasuda Nobuhiro675

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Tokyo Institute of Technology

4. Meguro-ku

5. Japan

6. Japan Synchrotron Radiation Research Institute

7. Hyogo 679-5198

Abstract

The lifetime of colored species of spiropyran derivatives increased significantly after the 2-cyanoethyl group was photoisomerized to the 1-cyanoethyl group on exposure to visible light.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Reference18 articles.

1. H. Duerr and H.Bouas-Laurent , Photochromism: Molecules and Systems , Elsevier , Amsterdam , 2003

2. J. C. Crano and R. J.Gugielmetti , Organic Photochromic and Thermochromic Compounds , Plenum Press , vol. 1 and 2 , 1999

3. Diarylethenes for Memories and Switches

4. Chemistry of Organic Photochromism , Kikan Kagaku Sosetsu, ed. Chemical Society of Japan , Scientific Society Press , 1996 , vol. 28

5. Elongated Lifetime of Unstable Colored Species by Intermolecular Hydrogen Bond Formation in Photochromic Crystals

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