Investigation of the preparation and reactivity of metal–organic frameworks of cerium and pyridine-2,4,6-tricarboxylate

Author:

Fonseca de Lima Juliana1ORCID,Moreno Fernanda V. S.1,Menezes Bruno A. T.1ORCID,da Silva Barbosa Jader2,Waddington Matthew C.3,Franklin Siân A.3,Clarkson Guy J.3ORCID,Walker Marc4ORCID,Serra Osvaldo A.2ORCID,Walton Richard I.3ORCID

Affiliation:

1. Instituto de Química, Universidade do Estado do Rio de Janeiro, 20550-900 Rio de Janeiro, Brazil

2. Departamento de Química, Faculdade de Filosofia, Ciências e Letras de Ribeirão Preto, Universidade de São Paulo, Avenida dos Bandeirantes, 3900, 14040-901, Ribeirão Preto, SP, Brazil

3. Department of Chemistry, University of Warwick, Coventry, CV4 7AL, UK

4. Department of Physics, University of Warwick, Coventry, CV4 7AL, UK

Abstract

Crystallisation of three coordination polymers of Ce3+ and pyridine-2,4,6-tricarboxylate is possible with the material formed depending on solvent and time of reaction: one is hydrothermally stable and shows redox and photocatalytic properties.

Funder

Fundação de Amparo à Pesquisa do Estado de São Paulo

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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