Spectroscopic and photophysical study of the demetallation of a zinc porphyrin and the aggregation of its free base in a tetraalkylphosphonium ionic liquid
Author:
Affiliation:
1. Department of Chemistry
2. University of Saskatchewan
3. Saskatoon, Canada
Abstract
Dissolving zinc tetraphenylporphyrin in the tetraalkylphosphonium chloride ionic liquid P4448Cl results in progressive demetallation of the solute and quantitative production of the free base porphyrin.
Funder
Natural Sciences and Engineering Research Council of Canada
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2014/CP/C4CP04257C
Reference46 articles.
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3. Ionogels, ionic liquid based hybrid materials
4. Ionic liquid solutions as extractive solvents for value-added compounds from biomass
5. Ionic liquid-based green processes for energy production
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