A direct route from white phosphorus and fluorous alkyl and aryl iodides to the corresponding trialkyl- and triarylphosphines
Author:
Affiliation:
1. Department of Chemistry
2. Texas A&M University
3. Texas 77843-3012
4. USA
5. Massachusetts Institute of Technology
6. Cambridge
Abstract
The title reaction is effected with samarium(ii) reductants that generate fluorous radicals that add to P4 with phosphorus–phosphorus bond cleavage.
Funder
Welch Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/QO/C8QO00943K
Reference75 articles.
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2. Handbook of Fluorous Chemistry , ed. J. A. Gladysz , D. P. Curran and I. T. Horváth , Wiley/VCH , Weinheim , 2004
3. Fluorous Chemistry , in Topics in Current Chemistry , ed. I. T. Horváth , 2012 , vol. 308
4. Phosphorus(III) ligands with fluorous ponytails
5. Preparation of polyfunctional phosphines using zinc organometallics
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