The influence of the alkoxy substituent length on the crystal structures of Tc(<scp>v</scp>) complexes with pyrazine-Reference-Cited by-同舟云学术

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The influence of the alkoxy substituent length on the crystal structures of Tc(v) complexes with pyrazine

Published:2024 Issue:12 Volume:26 Page:1747-1755
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Novikov Anton P.¹^ORCID,Volkov Mikhail A.¹^ORCID

Affiliation:

1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 31 Bldg. 4, Leninsky Prosp, Moscow, 119071, Russian Federation

Abstract

This paper reports the synthesis, X-ray and spectral characterization of pyrazine Tc(v) complexes with alkoxy ligands (from CH3 to C10H21). An increase in the chain length leads to a linear decrease in the decomposition temperature of the complex.

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CE/D4CE00029C

Reference53 articles.

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3. Higher Technetium(I) Carbonyls and Possibility of Using Them in Nuclear Medicine: Problems and Prospects

4. Hydrolysis of Hexacarbonyltechnetium(I) Cation: Formation and Structure of Technetium Carbonyl Hydride 99Tc3H(CO)14

5. Synthesis of technetium hydride TcH1.3 at 27 GPa

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