The magnetic properties of MAl4(OH)12SO4·3H2O with M = Co2+, Ni2+, and Cu2+determined by a combined experimental and computational approach-Reference-Cited by-同舟云学术

The magnetic properties of MAl₄(OH)₁₂SO₄·3H₂O with M = Co²⁺, Ni²⁺, and Cu²⁺determined by a combined experimental and computational approach

Published:2023 Issue:4 Volume:25 Page:3309-3322
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Andersen Anders B. A.¹^ORCID,Christiansen Rasmus Tang²^ORCID,Holm-Janas Sofie²^ORCID,Manvell Anna S.³^ORCID,Pedersen Kasper S.³^ORCID,Sheptyakov Denis⁴^ORCID,Embs Jan Peter⁴^ORCID,Jacobsen Henrik⁴^ORCID,Dachs Edgar⁵^ORCID,Vaara Juha⁶^ORCID,Lefmann Kim²^ORCID,Nielsen Ulla Gro¹^ORCID

Affiliation:

1. Department of Physics, Chemistry and Pharmacy, University of Southern Denmark, Campusvej 55, DK-5230 Odense, Denmark

2. Nanoscience Centre, Niels Bohr Institute, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen Ø, Denmark

3. Department of Chemistry, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark

4. Laboratory for Neutron Scattering and Imaging, Paul Scherrer Institut, CH-5232 Villigen PSI, Switzerland

5. Department of Chemistry and Physics of Materials, Universität Salzburg, Jakob-Haringerstrasse 2a, A-5020 Salzburg, Austria

6. NMR Research Unit, University of Oulu, FI-90014 Oulu, Finland

Abstract

CoAl4(OH)12(SO4)·3H2O is a 0D magnet and MAl4(OH)12(SO4)·3H2O with M = Ni2+and Cu2+are ferromagnetic spin chains (no magnetic ordering > 2 K) based on magnetic susceptibility, neutron scattering, NMR, and first-principles calculations.

Funder

Academy of Finland

Austrian Science Fund

Natur og Univers, Det Frie Forskningsråd

Kvantum-instituutti, Oulun Yliopisto

Horizon 2020 Framework Programme

Carlsbergfondet

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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