Synthesis, structure, and excited state kinetics of heteroleptic Cu(i) complexes with a new sterically demanding phenanthroline ligand

Author:

Kohler Lars1234,Hadt Ryan G.1234ORCID,Hayes Dugan1234ORCID,Chen Lin X.12345ORCID,Mulfort Karen L.1234ORCID

Affiliation:

1. Division of Chemical Sciences and Engineering

2. Argonne National Laboratory

3. Argonne

4. USA

5. Department of Chemistry

Abstract

In this report we describe the synthesis of a new phenanthroline ligand, 2,9-di(2,4,6-tri-isopropyl-phenyl)-1,10-phenanthroline (bL2) and its use as the blocking ligand in the preparation of two new heteroleptic Cu(i)diimine complexes.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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