Synthesis, characterization and catalytic epoxidation properties of lanthanide-stabilized peroxoisopolytungstates

Author:

Guo Jipeng12345ORCID,Niu Yanjun12345ORCID,Song Lanying12345,Xu Qiaofei12345ORCID,Lu Jingkun12345ORCID,Ma Pengtao12345,Zhang Dongdi12345ORCID,Zhang Chao12345,Niu Jingyang12345ORCID,Wang Jingping12345ORCID

Affiliation:

1. Henan Key Laboratory of Polyoxometalate Chemistry

2. Institute of Molecular and Crystal Engineering

3. College of Chemistry and Chemical Engineering

4. Henan University

5. Kaifeng

Abstract

A series of new lanthanide-containing peroxoisopolyoxotungstates, K6Na4[H32{Ln4(WO4)(H2O)16[W7O22(O2)2]4}3]·105H2O [Ln = CeIII(1), NdIII(2), SmIII(3), TbIII(4), ErIII(5)], have been successfully synthesized and structurally characterized.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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