Clathrates of TETROL: selective inclusion of methylcyclohexanones in their energetically unfavorable axial methyl conformations
Author:
Affiliation:
1. Department of Chemistry
2. Nelson Mandela Metropolitan University
3. Port Elizabeth 6031, South Africa
4. University of Cape Town
5. Rondebosch 7701, South Africa
Abstract
TETROL, surprisingly, includes 3- and 4-methylcyclohexanone exclusively in their energetically disfavoured axial conformations.
Funder
National Research Foundation
Nelson Mandela Metropolitan University
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2014/CC/C4CC06826B
Reference9 articles.
1. A computational, X-ray crystallographic and thermal stability analysis of TETROL and its pyridine and methylpyridine inclusion complexes
2. TADDOLs, Their Derivatives, and TADDOL Analogues: Versatile Chiral Auxiliaries
3. Enhanced enantioselectivity of 3-methylcyclohexanone by mixed diol host compounds
4. CH/? hydrogen bonds in crystals
5. Conformational studies oncyclohexanones
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