Light-driven reduction of aromatic olefins in aqueous media catalysed by aminopyridine cobalt complexes

Author:

Casadevall Carla1ORCID,Pascual David1,Aragón Jordi1,Call Arnau1ORCID,Casitas Alicia1,Casademont-Reig Irene2ORCID,Lloret-Fillol Julio13ORCID

Affiliation:

1. Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology, Avinguda Països Catalans 16, 43007 Tarragona, Spain

2. Donostia International Physics Center (DIPC), Polimero eta Material Aurreratuak: Fisika, Kimika eta Teknologia, Kimika Fakultatea, Euskal Herriko Unibertsitatea UPV/EHU, P.K. 1072, 20080 Donostia, Euskadi, Spain

3. Catalan Institution for Research and Advanced Studies (ICREA), Passeig Lluïs Companys, 23, 08010, Barcelona, Spain

Abstract

A dual catalytic system based on earth-abundant elements reduces aryl olefins to alkanes in aqueous media under visible light. Mechanistic studies allow for rational tunning of the system for the selective reduction of aryl olefins vs ketones and vice versa.

Funder

Generalitat de Catalunya

European Research Council

Ministerio de Ciencia e Innovación

Agencia Estatal de Investigación

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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