Green chemistry and first-principles theory enhance catalysis: synthesis and 6-fold catalytic activity increase of sub-5 nm Pd and Pt@Pd nanocubes-Reference-Cited by-同舟云学术

Green chemistry and first-principles theory enhance catalysis: synthesis and 6-fold catalytic activity increase of sub-5 nm Pd and Pt@Pd nanocubes

Published:2022 Issue:28 Volume:14 Page:10155-10168
ISSN:2040-3364
Container-title:Nanoscale
language:en
Short-container-title:Nanoscale

Author:

Mastronardi Valentina¹²,Kim Junseok³,Veronesi Marina⁴⁵,Pomili Tania¹²,Berti Francesco⁴,Udayan Gayatri⁶⁷,Brescia Rosaria⁸^ORCID,Diercks Justus S.⁹,Herranz Juan⁹^ORCID,Bandiera Tiziano⁴^ORCID,Fichthorn Kristen A.³^ORCID,Pompa Pier Paolo¹^ORCID,Moglianetti Mauro¹⁷^ORCID

Affiliation:

1. Nanobiointeractions & Nanodiagnostics, Istituto Italiano di Tecnologia, Via Morego 30, 16163 Genova, Italy

2. Department of Chemistry and Industrial Chemistry, University of Genova, Via Dodecaneso 31, 16146 Genova, Italy

3. Department of Chemical Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802, USA

4. D3-PharmaChemistry, Istituto Italiano di Tecnologia, 16163 Genoa, Italy

5. Structural Biophysics and Translational Pharmacology Facility, Istituto Italiano di Tecnologia, 16163 Genoa, Italy

6. Department of Engineering for Innovation, University of Salento, Via per Monteroni, 73100 Lecce, Italy

7. Center for Bio-Molecular Nanotechnologies, Istituto Italiano di Tecnologia, Via Barsanti 14, 73010 Arnesano (Lecce), Italy

8. Electron Microscopy Facility, Istituto Italiano di Tecnologia, Via Morego 30, 16163 Genova, Italy

9. Electrochemistry Laboratory, Paul Scherrer Institut, Forschungsstrasse 111, 5232 Villigen, Switzerland

Abstract

In this contribution we demonstrate the superior catalytic activity of citrate-coated sub-5 nm Pd and Pt@Pd nanocubes synthesized by harnessing the simulation-derived mechanism behind anisotropic growth.

Funder

U.S. Department of Energy

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NR/D2NR02278H

Reference87 articles.

1. Multifunctional Platinum@BSA–Rapamycin Nanocarriers for the Combinatorial Therapy of Cerebral Cavernous Malformation

2. Toward Cost-Effective and Sustainable Use of Precious Metals in Heterogeneous Catalysts