Finding the true pathway for reversible isomerization of a single azobenzene molecule tumbling on Au(111) surface-Reference-Cited by-同舟云学术

Finding the true pathway for reversible isomerization of a single azobenzene molecule tumbling on Au(111) surface

Published:2020 Issue:19 Volume:12 Page:10474-10479
ISSN:2040-3364
Container-title:Nanoscale
language:en
Short-container-title:Nanoscale

Author:

Xie Zhen¹²³⁴⁵^ORCID,Duan Sai⁶⁷⁸⁹¹⁰^ORCID,Wang Chuan-Kui¹²³⁴⁵,Luo Yi¹¹¹²¹³¹⁴¹⁵

Affiliation:

1. Shandong Province Key Laboratory of Medical Physics and Image Processing Technology

2. School of Physics and Electronics

3. Shandong Normal University

4. Jinan 250014

5. People's Republic of China

6. Collaborative Innovation Center of Chemistry for Energy Materials

7. Shanghai

8. Key Laboratory of Molecular Catalysis and Innovative Materials

9. MOE Key Laboratory of Computational Physical Sciences

10. Department of Chemistry

11. Department of Theoretical Chemistry and Biology

12. School of Engineering Sciences in Chemistry

13. Biotechnology and Health

14. KTH Royal Institute of Technology

15. S-106 91 Stockholm

Abstract

The in-situ cis structure of azobenzene adsorbed on Au(111) is identified, which accordingly exhibits a novel tumbling pathway of the trans–cis isomerization that overcomes two energy barriers.

Funder

Ministry of Science and Technology of the People's Republic of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

Link

http://pubs.rsc.org/en/content/articlepdf/2020/NR/D0NR01629B

Reference39 articles.

1. Making molecular machines work

2. Nanoparticles functionalised with reversible molecular and supramolecular switches

3. Molecular Switches and Motors on Surfaces

4. Photoresponsive Switches at Surfaces Based on Supramolecular Functionalization with Azobenzene-Oligoglycerol Conjugates

5. Inversion of the Rectifying Effect in Diblock Molecular Diodes by Protonation

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