Gas-phase structure of 1,8-bis[(trimethylsilyl)ethynyl]anthracene: cog-wheel-type vs. independent internal rotation and influence of dispersion interactions-Reference-Cited by-同舟云学术

Gas-phase structure of 1,8-bis[(trimethylsilyl)ethynyl]anthracene: cog-wheel-type vs. independent internal rotation and influence of dispersion interactions

Published:2017 Issue:20 Volume:19 Page:13093-13100
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Otlyotov Arseniy A.¹²³,Lamm Jan-Hendrik⁴⁵⁶⁷⁸^ORCID,Blomeyer Sebastian⁴⁵⁶⁷⁸^ORCID,Mitzel Norbert W.⁴⁵⁶⁷⁸^ORCID,Rybkin Vladimir V.⁹¹⁰¹¹¹²^ORCID,Zhabanov Yuriy A.¹²³,Tverdova Natalya V.¹²³,Giricheva Nina I.¹³¹⁴³,Girichev Georgiy V.¹²³

Affiliation:

1. Ivanovo State University of Chemistry and Technology

2. Ivanovo 153000

3. Russia

4. Universität Bielefeld

5. Fakultät für Chemie

6. Lehrstuhl für Anorganische Chemie und Strukturchemie

7. Centre for Molecular Materials CM2

8. D-33615 Bielefeld

9. University of Zurich

10. Department of Chemistry

11. CH-8057 Zürich

12. Switzerland

13. Ivanovo State University

14. Ivanovo 153025

Abstract

1,8-Bis[(trimethylsilyl)ethynyl]anthracene is extremely flexible and difficult to predict by DFT methods; gas electron diffraction plus molecular dynamics calculations enlighten competing intramolecular forces.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP01781B

Reference29 articles.

1. Photoluminescence and Electroluminescence of 9,10-Bis(silylethynyl)anthracene

2. Electroluminescent diodes from a single component emitting layer of dendritic macromolecules

3. Fluorescence and visual sensing of nitroaromatic explosives using electron rich discrete fluorophores