Lead(ii): Lewis acid and occasional base, as illustrated by its complex with 1,5-naphthalenedisulfonate and 5-methyl-1,10-phenanthroline
Author:
Affiliation:
1. ISIS
2. Université de Strasbourg
3. 67083 Strasbourg
4. France
5. NIMBE
6. CEA
7. CNRS
8. Université Paris-Saclay
9. 91191 Gif-sur-Yvette
Abstract
Hydrogen bonding to lead(ii) evidences the Lewis base character of this cation due to its valence shell lone pair.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01975K
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3. The origin of the stereochemically active Pb(II) lone pair: DFT calculations on PbO and PbS
4. Ab initiocalculation of the origin of the distortion of α-PbO
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