Role of inorganic layers on polysulfide decomposition at sodium-metal anode surfaces for room temperature Na/S batteries

Author:

Singsen Sirisak12,Ospina-Acevedo Francisco2,Suthirakun Suwit3ORCID,Hirunsit Pussana4,Balbuena Perla B.256ORCID

Affiliation:

1. School of Physics, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand

2. Department of Chemical Engineering, Texas A&M University, College Station, Texas 77843, USA

3. School of Chemistry, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand

4. National Nanotechnology Center (NANOTEC), National Science and Technology Development Agency (NSTDA), Pathum Thani, Thailand

5. Department of Materials Science and Engineering, Texas A&M University, College Station, Texas 77843, USA

6. Department of Chemistry, Texas A&M University, College Station, Texas 77843, USA

Abstract

Distinct passivation behavior was observed in thin SEI films of NaOH, Na2O, and Na2CO3 over Na metal surfaces attributed to the films’ electronic and structural properties and evolution; tested with a simulated molecular decomposition over the SEI.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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