Photoelectrochemical nickel-catalyzed carboacylation/silanoylation of alkenes with unactivated C/Si

Photoelectrochemical nickel-catalyzed carboacylation/silanoylation of alkenes with unactivated C/Si–H bonds

Published:2024 Issue:14 Volume:26 Page:8315-8322
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Wang Lanfen¹,Huo Xiangyu²,He Xiaozhi¹,Ackermann Lutz³^ORCID,Wang Dingyi¹^ORCID

Affiliation:

1. Department of Chemistry, College of Sciences, Northeastern University, Shenyang 110819, China

2. State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China

3. Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstraße 2, Göttingen 37077, Germany

Abstract

A photoelectrochemical approach for the carboacylation/silanoylation of alkenes with alkanes/hydrosilanes is described. The method offers a new perspective for chemists to rapidly obtain various ketones with high levels of structural complexity.

Funder

National Natural Science Foundation of China

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/GC/D3GC04109C

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