Copper-catalyzed umpolung Sonogashira-type coupling of arene boronic acids under visible light

Author:

Ma Jingwei1,Wang Qian1,Sun Yang2,Zhu Eva3,Li Xiaobao1,Tan Haibo14ORCID,Chen Guangying1,Zheng Chao1ORCID

Affiliation:

1. Key Laboratory of Tropical Medicinal Resources of Ministry of Education, Collaborative Innovation Center of Tropical Biological Resources, Hainan Normal University, Hainan Haikou 571158, China

2. Gordon Center for Medical Imaging, Department of Radiology, Massachusetts General Hospital and Harvard Medical School, Boston, MA02114, USA

3. Department of Radiology and Biomedical Imaging, Yale University School of Medicine, New Haven, CT 06520, USA

4. Key Laboratory of Plant Resources Conservation and Sustainable Utilization, Key Laboratory of South China Agricultural Plant Molecular Analysis, Guangdong Provincial Key Laboratory of Applied Botany, South China Botanical Garden, Chinese Academy of Sciences, Guangzhou 510650, China

Abstract

A copper-catalyzed alkynyl Csp–Csp2 coupling reaction of 1-alkynyl-1,2-benziodoxol-3(1H)-one and aryl or alkynyl boronic acids with a catalytic amount was developed under visible light irradiation.

Funder

National Natural Science Foundation of China

Hainan Normal University

Youth Innovation Promotion Association of the Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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