Oxido-molybdenum complexes obtained by Cl/O interchange between MoCl5 and carboxylic acids: a crystallographic, spectroscopic and computational study-Reference-Cited by-同舟云学术

Oxido-molybdenum complexes obtained by Cl/O interchange between MoCl5 and carboxylic acids: a crystallographic, spectroscopic and computational study

Published:2014 Issue:43 Volume:43 Page:16416-16423
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Bortoluzzi Marco¹²³,Marchetti Fabio⁴⁵⁶,Pampaloni Guido⁴⁵⁶,Zacchini Stefano⁷⁸⁹

Affiliation:

1. University of Venezia Ca’ Foscari

2. Dipartimento di Scienze Molecolari e Nanosistemi

3. I-30123 Venezia, Italy

4. University of Pisa

5. Dipartimento di Chimica e Chimica Industriale

6. I-56126 Pisa, Italy

7. University of Bologna

8. Dipartimento di Chimica Industriale “Toso Montanari”

9. I-40136 Bologna, Italy

Abstract

The reactivity of MoCl₅ with carboxylic acids has been elucidated for the first time. The reactions are featured by the chlorinating behaviour of MoCl₅, rather than affording the respective carboxylato complexes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT02201G

Reference88 articles.

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2. Reaction of titanium (IV) chloride with oxalic and succinic acids

3. The Reaction of Titanium Tetrachloride with acetic acid and 1-4 dioxane

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