Ultrathin single-ion sieving membrane with sub-1-nm channels for suppressing Li dendrite growth and polysulfide shuttling

Author:

Li Rongrong12,Wang Yichi13,Zhang Jingmin14,Yang Jun1,He Jiang14ORCID,Mai Wenjie15ORCID,Pu Xiong14ORCID

Affiliation:

1. CAS Center for Excellence in Nanoscience, Beijing Key Laboratory of Micro-Nano Energy and Sensor, Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, Beijing 101400, China

2. School of Physical Science, University of Chinese Academy of Sciences, Beijing 101408, China

3. Beijing National Center for Electron Microscopy and Laboratory of Advanced Materials, School of Materials Science and Engineering, Tsinghua University, Beijing, 100084, China

4. School of Nanoscience and Technology, University of Chinese Academy of Sciences, Beijing 100049, China

5. Siyuan Laboratory, Guangdong Provincial Engineering Technology Research Center of Vacuum Coating Technologies and New Energy Materials, Department of Physics, Jinan University, Guangzhou 510632, Guangdong, China

Abstract

Inspired by biomimetic channels, we construct a single-ion sieving membrane to suppress Li dendrite growth and polysulfide shuttling via synergizing sub-1-nm channel's size effect and charge effect.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Guangdong Province

National Key Research and Development Program of China

China Postdoctoral Science Foundation

Publisher

Royal Society of Chemistry (RSC)

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