The α-alkylation of ketones with alcohols in pure water catalyzed by a water-soluble Cp*Ir complex bearing a functional ligand-Reference-Cited by-同舟云学术

The α-alkylation of ketones with alcohols in pure water catalyzed by a water-soluble Cp*Ir complex bearing a functional ligand

Published:2019 Issue:35 Volume:43 Page:14057-14065
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Meng Chong¹²³⁴^ORCID,Xu Jing¹²³⁴^ORCID,Tang Yawen¹²³⁴^ORCID,Ai Yao¹²³⁴^ORCID,Li Feng¹²³⁴⁵^ORCID

Affiliation:

1. School of Chemical Engineering

2. Nanjing University of Science & Technology

3. Nanjing 210094

4. P. R. China

5. State Key Laboratory of Fine Chemicals

Abstract

A water-soluble dinuclear Cp*Ir complex bearing 4,4′,6,6′-tetrahydroxy-2,2′-bipyrimidine as a bridging ligand was found to be a highly effective catalyst for the α-alkylation of ketones with alcohols in water.

Funder

Natural Science Foundation of Jiangsu Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C9NJ03345A

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