P-Alkynyl functionalized benzazaphospholes as transmetalating agents-Reference-Cited by-同舟云学术

P-Alkynyl functionalized benzazaphospholes as transmetalating agents

Published:2021 Issue:2 Volume:50 Page:599-611
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhou Daniel Y.¹²³⁴,Miura-Akagi Preston M.¹²³⁴,McCarty Sierra M.¹²³⁴,Guiles Celeste H.¹²³⁴,O'Donnell Timothy J.¹²³⁴^ORCID,Yoshida Wesley Y.¹²³⁴,Krause Colleen E.¹⁵⁶⁴,Rheingold Arnold L.¹⁷⁸⁹⁴,Hughes Russell P.¹⁰¹¹¹¹²⁴,Cain Matthew F.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Hawai‘i at Mānoa

3. Honolulu

4. USA

5. University of Hartford

6. West Hartford

7. University of California

8. San Diego

9. La Jolla

10. 6128 Burke Laboratory

11. Dartmouth College

12. Hanover

Abstract

Exposure of 10π-electron benzazaphosphole 1 to HCl, followed by nucleophilic substitution with the Grignard reagent BrMgCCPh afforded alkynyl functionalized 3 featuring an exocyclic –CC–Ph group with an elongated P–C bond (1.7932(19) Å).

Funder

University of Hawai'i

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT01367F

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