Interaction-determined extraction capacity between rare earth ions and extractants: taking lanthanum and lutetium as models through theoretical calculations

Author:

Zheng Haifeng1,Li Yanling12,Zhang Xuyi34,Han Jinglu12,Li Songsong12,Wu Guolong12ORCID,Liu Qingshi12,Liu Xiaojuan124ORCID,Liao Wuping124ORCID

Affiliation:

1. State Key Laboratory of Rare Earth Resources Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022, People's Republic of China

2. University of Science and Technology of China, Hefei 230026, China

3. School of Chemistry and Chemical Engineering, Nanchang University, Nanchang, 330031, P. R. China

4. Ganjiang Innovation Academy, Chinese Academy of Sciences, Ganzhou 341000, China

Abstract

The extraction capacity is determined by the number of electrons transferred from a branched chain, which is conducive to the rapid design of a large number of new extractants.

Funder

National Safety Academic Fund

National Key Research and Development Program of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference100 articles.

1. Chemistry: Degrees of separation

2. U. S. Department of Energy , Critical Materials Strategy , Washington, DC , 2011 , pp. 1–191

3. Electro‐kinetic Separation of Rare Earth Elements Using a Redox‐Active Ligand

4. H.Humphries , Rare Earth Elements: The Global Supply Chain, Congressional Research Service , CRS Report R41347, Washington, DC , 2013 , pp. 1–26

5. Rare earth elements: Mendeleev’s bane, modern marvels

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