Broadening the chemical scope of laccases: selective deprotection of N-benzyl groups
Author:
Affiliation:
1. Department of Organic and Inorganic Chemistry
2. Biotechnology Institute of Asturias
3. University of Oviedo
4. 33006 Oviedo
5. Spain
Abstract
The chemoselective deprotection of N-benzylated primary amines, amino esters, diamines and amino alcohols in aqueous media using molecular oxygen as a mild oxidant has been demonstrated combining laccase from Trametes versicolor and TEMPO.
Publisher
Royal Society of Chemistry (RSC)
Subject
Pollution,Environmental Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/GC/C5GC00525F
Reference47 articles.
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2. Chiral Amine Synthesis: Methods, Developments and Applications, ed. T. C. Nugent, Wiley-VCH, Weinheim, 2010
3. Asymmetric synthesis of piperidines and octahydroindolizines using a one-pot ring-closure/N-debenzylation procedure
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