Visible-light-induced defluorinative allylation of difluoromethyl ketones using alkylamines as bifunctional agents-Reference-Cited by-同舟云学术

Visible-light-induced defluorinative allylation of difluoromethyl ketones using alkylamines as bifunctional agents

Published:2023 Issue:18 Volume:10 Page:4542-4549
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Jiao Xiaorui¹,Huang Zhonghou¹,Meng Weidong¹,Zhu Shengqing¹,Chu Lingling¹^ORCID

Affiliation:

1. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Chemistry and Chemical Engineering, Center for Advanced Low-Dimension Materials, Donghua University, Shanghai 201620, China

Abstract

A visible-light-induced alkylamine-facilitated reductive defluoroallylation of difluoromethyl ketones with allylic chlorides is reported, enabling efficient access to α-fluoro alkenylketones with high efficiency.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO00870C

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