Crystallographic structure and crystal field parameters in the [AnIV(DPA)3]2− series, An = Th, U, Np, Pu

Author:

Autillo Matthieu12345ORCID,Islam Md. Ashraful678910ORCID,Jung Julie11121314ORCID,Pilmé Julien157161710,Galland Nicolas187192010ORCID,Guerin Laetitia12345,Moisy Philippe12345ORCID,Berthon Claude12345ORCID,Tamain Christelle12345ORCID,Bolvin Hélène678910ORCID

Affiliation:

1. CEA

2. DES

3. ISEC

4. DMRC

5. Univ. Montpellier

6. Laboratoire de Chimie et Physique Quantiques

7. CNRS

8. Université Toulouse III

9. 31062 Toulouse

10. France

11. Theoretical division

12. Los Alamos National Laboratory

13. Los Alamos

14. USA

15. Sorbonne Université

16. Laboratoire de Chimie Théorique CC 137-4 place Jussieu

17. 75252 Paris Cédex 05

18. Université de Nantes

19. CEISAM UMR 6230

20. 44000 Nantes

Abstract

The [AnIV(DPA)3]2− series with An = Th, U, Np, Pu has been synthesized and characterized using SC-XRD, vibrational spectroscopy, and first principles calculations.

Funder

U.S. Department of Energy

Agence Nationale de la Recherche

Los Alamos National Laboratory

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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5. Emergence of californium as the second transitional element in the actinide series

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