Heterobimetallic complexes from 0D clusters to 3D networks based on various polycyanometallates and [Cu(dmpn)2]2+ (dmpn = 2,2-dimethyl-1,3-diaminopropane): synthesis, crystal structures and magnetic properties

Author:

Hao Xiaoyun1234,Shi Jingwen1234,Dou Yong1234,Cao Tong1234,Zhou Zhen1234,Yang Lu1234,Li Dacheng5678,Liu Qingyun910114,Jiang Jianzhuang1213148ORCID,Zhang Daopeng1234ORCID

Affiliation:

1. College of Chemical and Chemical Engineering

2. Shandong University of Technology

3. Zibo 255049

4. PR China

5. College of Chemical Engineering

6. Liaocheng University

7. Liaocheng 252059

8. China

9. College of Chemical and Environmental Engineering

10. Shandong University of Science and Technology

11. Qingdao 266510

12. Department of Chemistry

13. University of Science and Technology Beijing

14. Beijing 100083

Abstract

Six new cyanide-bridged complexes (0–3D) have been assembled by employing one copper compound and six cyano precursors. Investigation of the magnetic properties revealed the ferro- or antiferromagnetic coupling between FeIII/CrI ion and CuII ion.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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