Nickel-catalysed dehydrogenative coupling of aromatic diamines with alcohols: selective synthesis of substituted benzimidazoles and quinoxalines-Reference-Cited by-同舟云学术

Nickel-catalysed dehydrogenative coupling of aromatic diamines with alcohols: selective synthesis of substituted benzimidazoles and quinoxalines

Published:2019 Issue:42 Volume:55 Page:5958-5961
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Bera Atanu¹²³⁴⁵,Sk Motahar¹²³⁴⁵,Singh Khushboo¹²³⁴⁵,Banerjee Debasis¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Laboratory of Catalysis and Organic Synthesis

3. Indian Institute of Technology Roorkee

4. Roorkee-247667

5. India

Abstract

The nickel-catalysed dehydrogenative coupling of 1,2-di-amino-benzene with primary alcohols and diols for the synthesis of N-heterocycles is reported. The catalytic protocol enables the transformation in up to 91% yield and generates water and hydrogen gas as byproducts.

Funder

Science and Engineering Research Board

Indian Institute of Technology Roorkee

Department of Science and Technology, Ministry of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC02319D

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