[(η3-Bi3)2(IrCO)6(μ4-Bi)3]3−: a new archetype of a 15-vertex deltahedral hybrid from Bixx−-coordination aggregation of cationic [IrCO]+ units-Reference-Cited by-同舟云学术

[(η3-Bi3)2(IrCO)6(μ4-Bi)3]3−: a new archetype of a 15-vertex deltahedral hybrid from Bixx−-coordination aggregation of cationic [IrCO]+ units

Published:2019 Issue:32 Volume:48 Page:12013-12017
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Li Zhenyu¹²³⁴,Liu Caiping¹²³⁴,Wu Jie⁵⁶⁷⁸³,Lin Zian⁵⁶⁷⁸³^ORCID,Xu Li¹²³⁴^ORCID

Affiliation:

1. State Key Laboratory of Structural Chemistry

2. Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences

3. Fuzhou

4. P. R. China

5. Ministry of Education Key Laboratory of Analytical Science for Food Safety and Biology

6. Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety

7. College of Chemistry

8. Fuzhou University

Abstract

The first Zintl-deltahedral metal carbonyl hybrid [(η³-Bi₃)₂(IrCO)₆(μ₄-Bi)₃]³⁻ was obtained by a new synthetic methodology, namely the Bi_x^x−-coordination aggregation of [Ir(CO)]⁺ to trigonal prismatic [Ir(CO)]₆⁶⁺.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT02559F

Reference56 articles.

1. Polyatomic Zintl anions of the post-transition elements

2. Chemistry of Deltahedral Zintl Ions

3. Zintl Ions, Cage Compounds, and Intermetalloid Clusters of Group 14 and Group 15 Elements

4. From Clusters to Unorthodox Pnictogen Sources: Solution-Phase Reactivity of [E7]3–(E = P–Sb) Anions

5. Binary and Ternary Intermetalloid Clusters

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