Synthesis and isolation of non-chromophore cage-rearranged silsesquioxanes from base-catalyzed reactions
Author:
Affiliation:
1. Department of Chemistry
2. Center of Excellence for Innovation in Chemistry (PERCH-CIC)
3. Center for Catalysis
4. Center for Inorganic and Materials Chemistry
5. and Center of Intelligent Materials and Systems
Abstract
Carbonate (CO32−) anion as a stronger base but poorer in nucleophilicity gives rise exclusively to a cage expansion of unsubstituted products.
Funder
Thailand Research Fund
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT02585D
Reference24 articles.
1. Advanced functional materials based on polyhedral oligomeric silsesquioxane (POSS)
2. Recent Developments in the Chemistry of Cubic Polyhedral Oligosilsesquioxanes
3. Controlled Click-Assembly of Well-Defined Hetero-Bifunctional Cubic Silsesquioxanes and Their Application in Targeted Bioimaging
4. Bioconjugation on cube-octameric silsesquioxanes
5. POSS-derived solid acid catalysts with excellent hydrophobicity for highly efficient transformations of glycerol
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