Photolytic properties of cobalamins: a theoretical perspective-Reference-Cited by-同舟云学术

Photolytic properties of cobalamins: a theoretical perspective

Published:2016 Issue:11 Volume:45 Page:4457-4470
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kozlowski Pawel M.¹²³⁴⁵,Garabato Brady D.¹²³⁴,Lodowski Piotr⁶⁷⁸⁹¹⁰,Jaworska Maria⁶⁷⁸⁹¹⁰

Affiliation:

1. Department of Chemistry

2. University of Louisville

3. Kentucky 40292

4. USA

5. Visiting Professor, Department of Food Sciences

6. Department of Theoretical Chemistry

7. Institute of Chemistry

8. University of Silesia

9. PL-40 006 Katowice

10. Poland

Abstract

This Perspective Article highlights recent theoretical developments, and summarizes the current understanding of the photolytic properties of cobalamins from a computational point of view.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04286K

Reference108 articles.

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2. Adocobalamin (AdoCbl or coenzyme B12) cobalt-carbon bond homolysis radical-cage effects: product, kinetic, mechanistic, and cage efficiency factor (Fc) studies, plus the possibility that coenzyme B12-dependent enzymes function as "ultimate radical cages" and "ultimate radical traps"

3. Thermolysis of the cobalt-carbon bond of adenosylcobalamin. 2. Products, kinetics, and cobalt-carbon bond dissociation energy in aqueous solution

4. Methylcobalamin's Full- vs. Half-Strength Cobalt-Carbon sigma Bonds and Bond Dissociation Enthalpies: A>10^15 Co-CH3 Homolysis Rate Enhancement following One-Antibonding-Electron Reduction of Methlycobalamin

5. Listening to Reactive Intermediates: Application of Photoacoustic Calorimetry to Vitamin B12 Compounds

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