“Inverse” thermoresponse: heat-induced double-helix formation of an ethynylhelicene oligomer with tri(ethylene glycol) termini-Reference-Cited by-同舟云学术

“Inverse” thermoresponse: heat-induced double-helix formation of an ethynylhelicene oligomer with tri(ethylene glycol) termini

Published:2016 Issue:6 Volume:7 Page:3574-3580
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Saito Nozomi¹²³⁴⁵,Kobayashi Higashi¹²³⁴⁵,Yamaguchi Masahiko¹²³⁴⁵

Affiliation:

1. Department of Organic Chemistry

2. Graduate School of Pharmaceutical Sciences

3. Tohoku University

4. Sendai

5. Japan

Abstract

Ethynylhelicene oligomers with TEG terminal groups showed a unique thermoresponse in aqueous solvents: double-helix formation upon heating and disaggregation upon cooling.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC04959H

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4. Aromatic π-Stacking in Solution as Revealed through the Aggregation of Phenylacetylene Macrocycles

5. Host-guest complexation. 62. Solvophobic and entropic driving forces for forming velcraplexes, which are 4-fold, lock-key dimers in organic media

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