Determining Michael acceptor reactivity from kinetic, mechanistic, and computational analysis for the base-catalyzed thiol-Michael reaction-Reference-Cited by-同舟云学术

Determining Michael acceptor reactivity from kinetic, mechanistic, and computational analysis for the base-catalyzed thiol-Michael reaction

Published:2021 Issue:25 Volume:12 Page:3619-3628
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Huang Sijia¹²³⁴,Kim Kangmin⁵²³⁴^ORCID,Musgrave Grant M.¹²³⁴,Sharp Marcus¹²³⁴,Sinha Jasmine¹²³⁴^ORCID,Stansbury Jeffrey W.¹²³⁴⁶,Musgrave Charles B.¹²³⁴⁵,Bowman Christopher N.¹²³⁴⁶^ORCID

Affiliation:

1. Department of Chemical and Biological Engineering

2. University of Colorado Boulder

3. Boulder

4. USA

5. Department of Chemistry

6. Materials Science and Engineering Program

Abstract

A systematic investigation extends the fundamental understanding of the structure–property relationships between vinyl functionality and the reaction kinetics for the thiol-Michael reactions.

Funder

National Science Foundation

National Institute of Dental and Craniofacial Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2021/PY/D1PY00363A

Reference45 articles.

1. The Thiol-Michael Addition Click Reaction: A Powerful and Widely Used Tool in Materials Chemistry

2. Thiol-click chemistry: a multifaceted toolbox for small molecule and polymer synthesis