A “waiting” carbon nitride radical anion: a charge storage material and key intermediate in direct C–H thiolation of methylarenes using elemental sulfur as the “S”-source-Reference-Cited by-同舟云学术

A “waiting” carbon nitride radical anion: a charge storage material and key intermediate in direct C–H thiolation of methylarenes using elemental sulfur as the “S”-source

Published:2018 Issue:14 Volume:9 Page:3584-3591
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Savateev Aleksandr¹²³⁴^ORCID,Kurpil Bogdan¹²³⁴^ORCID,Mishchenko Artem⁵⁶⁷⁸,Zhang Guigang¹²³⁴^ORCID,Antonietti Markus¹²³⁴

Affiliation:

1. Department of Colloid Chemistry

2. Max-Planck Institute of Colloids and Interfaces

3. 14476 Potsdam

4. Germany

5. Department for Heterophase Synthesis of Inorganic Compounds and Materials

6. V.I. Vernadsky Institute of General and Inorganic Chemistry

7. Kiev

8. Ukraine

Abstract

Potassium poly(heptazine imide), a carbon nitride semiconductor, in the presence of hole scavengers and visible light gives stable radical anion with the specific density of unpaired electrons reaching 112 mmol g⁻¹.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC00745D

Reference48 articles.

1. Understanding and exploiting C–H bond activation

2. Conjugated Polymers: Catalysts for Photocatalytic Hydrogen Evolution

3. A Facile Band Alignment of Polymeric Carbon Nitride Semiconductors to Construct Isotype Heterojunctions