Complexation of 2,7-diazapyrene with boron for structural and electronic tuning

Author:

Nakazato Takumi12345,Shinokubo Hiroshi12345ORCID,Miyake Yoshihiro12345ORCID

Affiliation:

1. Department of Molecular and Macromolecular Chemistry

2. Graduate School of Engineering

3. Nagoya University

4. Nagoya 464-8603

5. Japan

Abstract

Complexation of tetra(hydroxyphenyl)-2,7-diazapyrene with boron provided the boron complexes as anti- and syn-isomers. The structural difference induces self-association behaviour of the syn-isomer and isomerisation of the anti-isomer in the solution and solid states.

Funder

Japan Society for the Promotion of Science

Ministry of Education, Culture, Sports, Science and Technology

Nagoya University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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