A tetra Co(<scp>ii</scp>/<scp>iii</scp>) complex with an open cubane Co<sub>4</sub>O<sub>4</sub> core and square-pyramidal Co(<scp>ii</scp>) and octahedral Co(<scp>iii</scp>) centres: bifunctional electrocatalytic activity towards water splitting at neutral pH-Reference-Cited by-同舟云学术

A tetra Co(ii/iii) complex with an open cubane Co₄O₄ core and square-pyramidal Co(ii) and octahedral Co(iii) centres: bifunctional electrocatalytic activity towards water splitting at neutral pH

Published:2022 Issue:11 Volume:51 Page:4510-4521
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Srivastava Ankit Kumar¹,Mondal Arpan²^ORCID,Konar Sanjit²^ORCID,Pal Samudranil¹^ORCID

Affiliation:

1. School of Chemistry, University of Hyderabad, Hyderabad 500 046, India

2. Department of Chemistry, Indian Institute of Science Education and Research Bhopal, Bhopal 462066, India

Abstract

A paramagnetic and redox active open cubane Co4O4 core containing complex [CoIICoIII(μ-OAc)(μ3-OH)(μ-L)]2 (L3− = ONONO-donor compartmental ligand) and its heterogeneous electrocatalytic activity for water splitting at neutral pH are reported.

Funder

University Grants Commission

Indian Institute of Science Education and Research Bhopal

Science and Engineering Research Board

Ministry of Education, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT04086C

Reference111 articles.